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A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol

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dc.contributor.author Wellington, Kevin W
dc.contributor.author Govindjee, Varsha P
dc.contributor.author Steenkamp, Paul
dc.date.accessioned 2019-03-07T09:48:15Z
dc.date.available 2019-03-07T09:48:15Z
dc.date.issued 2018-12
dc.identifier.citation Wellington, K.W., Govindjee, V.P., Steenkamp, P. 2018. A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. Journal of Catalysis, v. 368, pp 306-314. en_US
dc.identifier.issn 0021-9517
dc.identifier.uri http://hdl.handle.net/10204/10753
dc.description Copyright: 2018 Elsevier. Due to copyright restrictions, the attached PDF file contains the abstract of the published item only. For access to the published item, kindly consult the publisher's website. The definitive version of the is published at https://doi.org/10.1016/j.jcat.2018.10.014 en_US
dc.description.abstract A commercial laccase, Suberase from Novozymes, catalyses the synthesis of triaminated cyclohexa-2,4-dienones and a methylbenzene-1,2-diol derivative. The primary amine (analine) and the catechol was reacted under mild conditions (40C) in a reaction vessel open to air in the presence of Suberase and a co-solvent (DMF) at pH 6.0. This reaction was also conducted using an environmentally friendly cosolvent (EtOH). Triamination is favoured over diamination and monoamination. en_US
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.relation.ispartofseries Worklist;21709
dc.subject Laccase en_US
dc.subject Catechols en_US
dc.subject Analines en_US
dc.subject Cyclohexa-2,4-dienones en_US
dc.subject C-N bond formation en_US
dc.subject Green chemistry en_US
dc.title A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol en_US
dc.type Article en_US
dc.identifier.apacitation Wellington, K. W., Govindjee, V. P., & Steenkamp, P. (2018). A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. http://hdl.handle.net/10204/10753 en_ZA
dc.identifier.chicagocitation Wellington, Kevin W, Varsha P Govindjee, and Paul Steenkamp "A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol." (2018) http://hdl.handle.net/10204/10753 en_ZA
dc.identifier.vancouvercitation Wellington KW, Govindjee VP, Steenkamp P. A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. 2018; http://hdl.handle.net/10204/10753. en_ZA
dc.identifier.ris TY - Article AU - Wellington, Kevin W AU - Govindjee, Varsha P AU - Steenkamp, Paul AB - A commercial laccase, Suberase from Novozymes, catalyses the synthesis of triaminated cyclohexa-2,4-dienones and a methylbenzene-1,2-diol derivative. The primary amine (analine) and the catechol was reacted under mild conditions (40C) in a reaction vessel open to air in the presence of Suberase and a co-solvent (DMF) at pH 6.0. This reaction was also conducted using an environmentally friendly cosolvent (EtOH). Triamination is favoured over diamination and monoamination. DA - 2018-12 DB - ResearchSpace DP - CSIR KW - Laccase KW - Catechols KW - Analines KW - Cyclohexa-2,4-dienones KW - C-N bond formation KW - Green chemistry LK - https://researchspace.csir.co.za PY - 2018 SM - 0021-9517 T1 - A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol TI - A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol UR - http://hdl.handle.net/10204/10753 ER - en_ZA


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