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Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium

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dc.contributor.author Rohwer, Mark B
dc.contributor.author Modibedi, Remegia M
dc.contributor.author Ozoemena, KI
dc.date.accessioned 2015-11-20T12:19:27Z
dc.date.available 2015-11-20T12:19:27Z
dc.date.issued 2015-02
dc.identifier.citation Rohwer, M.B, Modibedi, R.M and Ozoemena, K.I. 2015. Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium. Electroanalysis, vol. 27, pp 957-963 en_US
dc.identifier.issn 1040-0397
dc.identifier.uri http://onlinelibrary.wiley.com/doi/10.1002/elan.201400707/abstract
dc.identifier.uri http://hdl.handle.net/10204/8298
dc.description Copyright: 2015 Wiley. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Electroanalysis, vol. 27, pp 957-963 en_US
dc.description.abstract The impact of microwave irradiation on the structure and electrochemistry of monodispersed palladium nanoparticles is reported for the first time. When compared to the Pd that was not subjected to microwave treatment, the microwaved Pd nanocatalyst gave higher electrochemical active surface area (EASA= 67 m(SUP2)g(SUP-1), aggregation/uniformity of dispersion, showed higher amount of the palladium oxides, and showed remarkable electrocatalytic behaviour towards ethanol oxidation reaction in alkaline medium (in terms of high mass activity stability and fast reaction kinetics). The remarkable microwave-induced properties on the Pd catalyst promise to revolutionize the use of microwave for catalyst activation for enhanced heterogeneous catalysis and fuel cell chemistry. en_US
dc.language.iso en en_US
dc.publisher Wiley en_US
dc.relation.ispartofseries Workflow;15864
dc.subject Pd nanoparticles en_US
dc.subject Microwave irradiation en_US
dc.subject Ethanol oxidation en_US
dc.title Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium en_US
dc.type Article en_US
dc.identifier.apacitation Rohwer, M. B., Modibedi, R. M., & Ozoemena, K. (2015). Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium. http://hdl.handle.net/10204/8298 en_ZA
dc.identifier.chicagocitation Rohwer, Mark B, Remegia M Modibedi, and KI Ozoemena "Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium." (2015) http://hdl.handle.net/10204/8298 en_ZA
dc.identifier.vancouvercitation Rohwer MB, Modibedi RM, Ozoemena K. Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium. 2015; http://hdl.handle.net/10204/8298. en_ZA
dc.identifier.ris TY - Article AU - Rohwer, Mark B AU - Modibedi, Remegia M AU - Ozoemena, KI AB - The impact of microwave irradiation on the structure and electrochemistry of monodispersed palladium nanoparticles is reported for the first time. When compared to the Pd that was not subjected to microwave treatment, the microwaved Pd nanocatalyst gave higher electrochemical active surface area (EASA= 67 m(SUP2)g(SUP-1), aggregation/uniformity of dispersion, showed higher amount of the palladium oxides, and showed remarkable electrocatalytic behaviour towards ethanol oxidation reaction in alkaline medium (in terms of high mass activity stability and fast reaction kinetics). The remarkable microwave-induced properties on the Pd catalyst promise to revolutionize the use of microwave for catalyst activation for enhanced heterogeneous catalysis and fuel cell chemistry. DA - 2015-02 DB - ResearchSpace DP - CSIR KW - Pd nanoparticles KW - Microwave irradiation KW - Ethanol oxidation LK - https://researchspace.csir.co.za PY - 2015 SM - 1040-0397 T1 - Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium TI - Microwave activation of palladium nanoparticles for enhanced ethanol electrocatalytic oxidation reaction in alkaline medium UR - http://hdl.handle.net/10204/8298 ER - en_ZA


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