dc.contributor.author |
Cordeiro, N
|
|
dc.contributor.author |
Gouveia, C
|
|
dc.contributor.author |
Jacob John, Maya
|
|
dc.date.accessioned |
2012-04-11T07:52:18Z |
|
dc.date.available |
2012-04-11T07:52:18Z |
|
dc.date.issued |
2011-01 |
|
dc.identifier.citation |
Cordeiro, N, Gouveia, C and Jacob John, M. 2011. Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography. Industrial Crops and Products, vol. 33(1), pp 108-115 |
en_US |
dc.identifier.issn |
0926-6690 |
|
dc.identifier.uri |
http://www.sciencedirect.com/science/article/pii/S0926669010002189
|
|
dc.identifier.uri |
http://hdl.handle.net/10204/5727
|
|
dc.description |
Copyright: 2011 Elsevier. This is the accepted version of the work. The definitive version is published in Industrial Crops and Products, vol. 33(1), pp 108-115 |
en_US |
dc.description.abstract |
Inverse gas chromatography (IGC) is a suitable method to determine surface energy of natural fibres when compared to wetting techniques. In the present study, the surface properties of raw and modified lignocellulosic fibres have been investigated by IGC. The fibres chosen for the study were flax, hemp, kenaf, agave, agave hybrid, sisal and pineapple. The treatments used were 4% NaOH and 2% zein. The uniqueness of zein treatment is that it is bio-based and therefore maintains the biodegradable character of the natural fibres. Fourier transform infrared spectroscopy (FTIR) and environmental scanning electron microscope (ESEM) were also performed to characterize the surface changes in fibres. The surface properties of fibres are influenced by the chemical composition, crystallinity and morphology of the fibres. Bast fibres exhibited higher surface dispersive energy than leaf fibres. The raw fibres have a predominant basic character, whereas the alkaline treatment makes the fibres more acidic. Both alkaline and zein treatments decrease the dispersive surface energy and the specific free energy of adsorption. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsevier |
en_US |
dc.relation.ispartofseries |
Workflow;7898 |
|
dc.subject |
Natural fibres |
en_US |
dc.subject |
Fibres modification |
en_US |
dc.subject |
Alkaline treatment |
en_US |
dc.subject |
Zein treatment |
en_US |
dc.subject |
Inverse gas chromatography |
en_US |
dc.subject |
Surface properties |
en_US |
dc.title |
Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Cordeiro, N., Gouveia, C., & Jacob John, M. (2011). Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography. http://hdl.handle.net/10204/5727 |
en_ZA |
dc.identifier.chicagocitation |
Cordeiro, N, C Gouveia, and Maya Jacob John "Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography." (2011) http://hdl.handle.net/10204/5727 |
en_ZA |
dc.identifier.vancouvercitation |
Cordeiro N, Gouveia C, Jacob John M. Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography. 2011; http://hdl.handle.net/10204/5727. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Cordeiro, N
AU - Gouveia, C
AU - Jacob John, Maya
AB - Inverse gas chromatography (IGC) is a suitable method to determine surface energy of natural fibres when compared to wetting techniques. In the present study, the surface properties of raw and modified lignocellulosic fibres have been investigated by IGC. The fibres chosen for the study were flax, hemp, kenaf, agave, agave hybrid, sisal and pineapple. The treatments used were 4% NaOH and 2% zein. The uniqueness of zein treatment is that it is bio-based and therefore maintains the biodegradable character of the natural fibres. Fourier transform infrared spectroscopy (FTIR) and environmental scanning electron microscope (ESEM) were also performed to characterize the surface changes in fibres. The surface properties of fibres are influenced by the chemical composition, crystallinity and morphology of the fibres. Bast fibres exhibited higher surface dispersive energy than leaf fibres. The raw fibres have a predominant basic character, whereas the alkaline treatment makes the fibres more acidic. Both alkaline and zein treatments decrease the dispersive surface energy and the specific free energy of adsorption.
DA - 2011-01
DB - ResearchSpace
DP - CSIR
KW - Natural fibres
KW - Fibres modification
KW - Alkaline treatment
KW - Zein treatment
KW - Inverse gas chromatography
KW - Surface properties
LK - https://researchspace.csir.co.za
PY - 2011
SM - 0926-6690
T1 - Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography
TI - Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography
UR - http://hdl.handle.net/10204/5727
ER -
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en_ZA |