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Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone

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dc.contributor.author Rademeyer, M
dc.contributor.author Van Heerden, FR
dc.contributor.author Van Der Merwe, MM
dc.date.accessioned 2009-02-12T08:19:50Z
dc.date.available 2009-02-12T08:19:50Z
dc.date.issued 2009-01
dc.identifier.citation Rademeyer, M. 2009. Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. Acta Crystallographica Section E, Vol. 65(1), pp 7 en
dc.identifier.issn 1600-5368
dc.identifier.uri http://hdl.handle.net/10204/2982
dc.description Copyright: 2009 International Union of Crystallography en
dc.description.abstract The three-ring eudesmanolide, C15H16O3, is a natural product isolated from Dicoma anomala Sond. (Asteraceae). The compound contains an endo-exo cross conjugated methylenecyclohexenone ring with an envelope conformation trans-fused with cyclohexane and trans-annelated with an -methylene -lactone. The absolute structure was assigned by optical rotation measurements compared to those from the synthetic compound with known stereochemistry. The crystal packing is consolidated by C-HO interactions en
dc.language.iso en en
dc.publisher International Union of Crystallography en
dc.subject Dehydrobrachylaenolide en
dc.subject Single-crystal X-ray study en
dc.subject Mean sigma(C–C) = 0.002 A° en
dc.subject R factor = 0.033 en
dc.subject wR factor = 0.095 en
dc.subject Data-to-parameter ratio = 14.1 en
dc.subject T = 150 K; en
dc.title Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone en
dc.type Article en
dc.identifier.apacitation Rademeyer, M., Van Heerden, F., & Van Der Merwe, M. (2009). Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. http://hdl.handle.net/10204/2982 en_ZA
dc.identifier.chicagocitation Rademeyer, M, FR Van Heerden, and MM Van Der Merwe "Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone." (2009) http://hdl.handle.net/10204/2982 en_ZA
dc.identifier.vancouvercitation Rademeyer M, Van Heerden F, Van Der Merwe M. Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. 2009; http://hdl.handle.net/10204/2982. en_ZA
dc.identifier.ris TY - Article AU - Rademeyer, M AU - Van Heerden, FR AU - Van Der Merwe, MM AB - The three-ring eudesmanolide, C15H16O3, is a natural product isolated from Dicoma anomala Sond. (Asteraceae). The compound contains an endo-exo cross conjugated methylenecyclohexenone ring with an envelope conformation trans-fused with cyclohexane and trans-annelated with an -methylene -lactone. The absolute structure was assigned by optical rotation measurements compared to those from the synthetic compound with known stereochemistry. The crystal packing is consolidated by C-HO interactions DA - 2009-01 DB - ResearchSpace DP - CSIR KW - Dehydrobrachylaenolide KW - Single-crystal X-ray study KW - Mean sigma(C–C) = 0.002 A° KW - R factor = 0.033 KW - wR factor = 0.095 KW - Data-to-parameter ratio = 14.1 KW - T = 150 K; LK - https://researchspace.csir.co.za PY - 2009 SM - 1600-5368 T1 - Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone TI - Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone UR - http://hdl.handle.net/10204/2982 ER - en_ZA


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