dc.contributor.author |
Rademeyer, M
|
|
dc.contributor.author |
Van Heerden, FR
|
|
dc.contributor.author |
Van Der Merwe, MM
|
|
dc.date.accessioned |
2009-02-12T08:19:50Z |
|
dc.date.available |
2009-02-12T08:19:50Z |
|
dc.date.issued |
2009-01 |
|
dc.identifier.citation |
Rademeyer, M. 2009. Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. Acta Crystallographica Section E, Vol. 65(1), pp 7 |
en |
dc.identifier.issn |
1600-5368 |
|
dc.identifier.uri |
http://hdl.handle.net/10204/2982
|
|
dc.description |
Copyright: 2009 International Union of Crystallography |
en |
dc.description.abstract |
The three-ring eudesmanolide, C15H16O3, is a natural product isolated from Dicoma anomala Sond. (Asteraceae). The compound contains an endo-exo cross conjugated methylenecyclohexenone ring with an envelope conformation trans-fused with cyclohexane and trans-annelated with an -methylene -lactone. The absolute structure was assigned by optical rotation measurements compared to those from the synthetic compound with known stereochemistry. The crystal packing is consolidated by C-HO interactions |
en |
dc.language.iso |
en |
en |
dc.publisher |
International Union of Crystallography |
en |
dc.subject |
Dehydrobrachylaenolide |
en |
dc.subject |
Single-crystal X-ray study |
en |
dc.subject |
Mean sigma(C–C) = 0.002 A° |
en |
dc.subject |
R factor = 0.033 |
en |
dc.subject |
wR factor = 0.095 |
en |
dc.subject |
Data-to-parameter ratio = 14.1 |
en |
dc.subject |
T = 150 K; |
en |
dc.title |
Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone |
en |
dc.type |
Article |
en |
dc.identifier.apacitation |
Rademeyer, M., Van Heerden, F., & Van Der Merwe, M. (2009). Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. http://hdl.handle.net/10204/2982 |
en_ZA |
dc.identifier.chicagocitation |
Rademeyer, M, FR Van Heerden, and MM Van Der Merwe "Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone." (2009) http://hdl.handle.net/10204/2982 |
en_ZA |
dc.identifier.vancouvercitation |
Rademeyer M, Van Heerden F, Van Der Merwe M. Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone. 2009; http://hdl.handle.net/10204/2982. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Rademeyer, M
AU - Van Heerden, FR
AU - Van Der Merwe, MM
AB - The three-ring eudesmanolide, C15H16O3, is a natural product isolated from Dicoma anomala Sond. (Asteraceae). The compound contains an endo-exo cross conjugated methylenecyclohexenone ring with an envelope conformation trans-fused with cyclohexane and trans-annelated with an -methylene -lactone. The absolute structure was assigned by optical rotation measurements compared to those from the synthetic compound with known stereochemistry. The crystal packing is consolidated by C-HO interactions
DA - 2009-01
DB - ResearchSpace
DP - CSIR
KW - Dehydrobrachylaenolide
KW - Single-crystal X-ray study
KW - Mean sigma(C–C) = 0.002 A°
KW - R factor = 0.033
KW - wR factor = 0.095
KW - Data-to-parameter ratio = 14.1
KW - T = 150 K;
LK - https://researchspace.csir.co.za
PY - 2009
SM - 1600-5368
T1 - Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone
TI - Dehydrobrachylaenolide: an eudesmanetype sesquiterpene lactone
UR - http://hdl.handle.net/10204/2982
ER -
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en_ZA |