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Please use this identifier to cite or link to this item: http://hdl.handle.net/10204/1911

Title: Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical
Authors: Vleggaar, R
Horak, RM
Maharaj, VJ
Keywords: Stereochemical courses
Fumitremorgin-B
Verruculogen
Pennicillium-metabolites
Verruculosum investigations
Issue Date: Feb-1993
Publisher: Royal Society of Chemistry
Citation: Vleggaar, R, et al. 1993. Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. Journal of the Chemical Society-Chemical Communications, Issue 3, pp 274-275
Abstract: Incorporation studies of [2-(2)H(3),2-(13)C].acetate and different [2H, 13C]-labelled mevalonolactones into verruculogen established the stereochemical course of ring C formation in fumitremorgin B, which results in the loss of stereochemical integrity of the C-22 methyl groups, and of the formation of the eight-membered peroxide ring at C-25 in verruculogen.
URI: http://hdl.handle.net/10204/1911
http://hdl.handle.net/10204/1911
ISSN: 0022-4936
Appears in Collections:General science, engineering & technology
Discovery chemistry

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