Estimating the gas permeability of commercial volatile corrosion inhibitors at elevated temperatures with thermo-gravimetry

Abstract

Volatile corrosion inhibitors (VCIs) are incorporated into packaging paper or film to protect metals against atmospheric corrosion. The vapour pressure determines the equilibrium concentration of a volatile corrosion inhibitor (VCI) in the surrounding atmosphere. However, the rate at which the VCI can be delivered across the air gap to a metal surface is determined by the gas permeability. This is the product of the vapour pressure and the diffusion coefficient: S-A = PADAB. The gas permeability of commercial VCIs was estimated at elevated temperatures from vaporisation rates measured using a simple thermo-gravimetric method (TG).