Vleggaar, RHorak, RMMaharaj, VJ2007-03-142007-06-072007-03-142007-06-071993-02Vleggaar, R, et al. 1993. Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. Journal of the Chemical Society-Chemical Communications, Issue 3, pp 274-2750022-4936http://hdl.handle.net/10204/1911http://hdl.handle.net/10204/1911Incorporation studies of [2-(2)H(3),2-(13)C].acetate and different [2H, 13C]-labelled mevalonolactones into verruculogen established the stereochemical course of ring C formation in fumitremorgin B, which results in the loss of stereochemical integrity of the C-22 methyl groups, and of the formation of the eight-membered peroxide ring at C-25 in verruculogen.190180 bytesapplication/pdfenCopyright: 1993 Royal Society of ChemistryStereochemical coursesFumitremorgin-BVerruculogenPennicillium-metabolitesVerruculosum investigationsStereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemicalArticleVleggaar, R., Horak, R., & Maharaj, V. (1993). Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. http://hdl.handle.net/10204/1911Vleggaar, R, RM Horak, and VJ Maharaj "Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical." (1993) http://hdl.handle.net/10204/1911Vleggaar R, Horak R, Maharaj V. Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. 1993; http://hdl.handle.net/10204/1911.TY - Article AU - Vleggaar, R AU - Horak, RM AU - Maharaj, VJ AB - Incorporation studies of [2-(2)H(3),2-(13)C].acetate and different [2H, 13C]-labelled mevalonolactones into verruculogen established the stereochemical course of ring C formation in fumitremorgin B, which results in the loss of stereochemical integrity of the C-22 methyl groups, and of the formation of the eight-membered peroxide ring at C-25 in verruculogen. DA - 1993-02 DB - ResearchSpace DP - CSIR KW - Stereochemical courses KW - Fumitremorgin-B KW - Verruculogen KW - Pennicillium-metabolites KW - Verruculosum investigations LK - https://researchspace.csir.co.za PY - 1993 SM - 0022-4936 T1 - Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical TI - Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical UR - http://hdl.handle.net/10204/1911 ER -