Kumar, NeerajRay, Suprakas SNgila, JC2018-07-312018-07-312018-10Kumar, N., Ray, S.S. and Ngila, J.C. 2017. Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance. New Journal of Chemistry, vol 41, pp 14618-146261144-05461369-9261http://pubs.rsc.org/en/content/articlelanding/2017/nj/c7nj03295a#!divAbstracthttp://hdl.handle.net/10204/10334Copyright: 2017. Royal Society of Chemistry. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Journal of New Journal of Chemistry, vol 41, pp 14618-14626Herein, Ag(subscript2)Te and Ag/Ag(subscript2)Te nanocrystals were synthesised via a hydrothermal method using diphenyl ditelluride as a new tellurium source and 1-butyl-3-methyl imidazolium acetate (BMIA IL) as a structure controlling and conducting coating source. The as-synthesized nanocrystals were characterized via XRD, SEM-EDS, XPS, TEM, FTIR, UV-vis, and PL measurements. The photocatalytic behaviour of the Ag(subscript2)Te and Ag/Ag(subscript2)Te nanocrystals was investigated for the degradation of methylene blue in the presence of UV-visible light. After 90 minutes of photo-irradiation, up to 95.74% of the dye was photocatalytically degraded by the Ag/Ag(subscript2)Te nanocrystals. This improved photocatalytic activity was achieved due to the effective charge separation, synergic effect of the Ag(subscript2)Te semiconductor and plasmonic metallic Ag, conducting BMIA IL coating, and morphological features of the nanocrystals. The appearance of strong peaks in the photoluminescence emission spectra at room temperature suggests a high-level transition in the prepared plasmonic photocatalyst system. The enhanced photocatalytic mechanism for dye degradation using the Ag/Ag(subscript2)Te nanocrystals has also been described. Thus, the present report presents new insight into the design and development of Ag/Ag(subscript2)Te plasmonic photocatalysts for environmental applications.enNanocrystalsAg2TePhotocatalytic activitySilver tellurideArticleKumar, N., Ray, S. S., & Ngila, J. (2018). Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance. http://hdl.handle.net/10204/10334Kumar, Neeraj, Suprakas S Ray, and JC Ngila "Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance." (2018) http://hdl.handle.net/10204/10334Kumar N, Ray SS, Ngila J. Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance. 2018; http://hdl.handle.net/10204/10334.TY - Article AU - Kumar, Neeraj AU - Ray, Suprakas S AU - Ngila, JC AB - Herein, Ag(subscript2)Te and Ag/Ag(subscript2)Te nanocrystals were synthesised via a hydrothermal method using diphenyl ditelluride as a new tellurium source and 1-butyl-3-methyl imidazolium acetate (BMIA IL) as a structure controlling and conducting coating source. The as-synthesized nanocrystals were characterized via XRD, SEM-EDS, XPS, TEM, FTIR, UV-vis, and PL measurements. The photocatalytic behaviour of the Ag(subscript2)Te and Ag/Ag(subscript2)Te nanocrystals was investigated for the degradation of methylene blue in the presence of UV-visible light. After 90 minutes of photo-irradiation, up to 95.74% of the dye was photocatalytically degraded by the Ag/Ag(subscript2)Te nanocrystals. This improved photocatalytic activity was achieved due to the effective charge separation, synergic effect of the Ag(subscript2)Te semiconductor and plasmonic metallic Ag, conducting BMIA IL coating, and morphological features of the nanocrystals. The appearance of strong peaks in the photoluminescence emission spectra at room temperature suggests a high-level transition in the prepared plasmonic photocatalyst system. The enhanced photocatalytic mechanism for dye degradation using the Ag/Ag(subscript2)Te nanocrystals has also been described. Thus, the present report presents new insight into the design and development of Ag/Ag(subscript2)Te plasmonic photocatalysts for environmental applications. DA - 2018-10 DB - ResearchSpace DP - CSIR KW - Nanocrystals KW - Ag2Te KW - Photocatalytic activity KW - Silver telluride LK - https://researchspace.csir.co.za PY - 2018 SM - 1144-0546 SM - 1369-9261 T1 - Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance TI - Ionic liquid-assisted synthesis of Ag/Ag2Te nanocrystals via a hydrothermal route for enhanced photocatalytic performance UR - http://hdl.handle.net/10204/10334 ER -