Makgwane, Peter RRay, SS2014-09-222014-09-222014-09Makgwane, P.R and Ray, S.S. 2014. Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. Catalysis Communications, vol. 54(5), pp 118-1231566-7367http://ac.els-cdn.com/S156673671400212X/1-s2.0-S156673671400212X-main.pdf?_tid=1813d16c-3fe4-11e4-bf03-00000aacb35f&acdnat=1411121141_37c250b8b1098cb00f4ea110e1a684c5http://hdl.handle.net/10204/7682https://www.sciencedirect.com/science/article/pii/S156673671400212Xhttps://doi.org/10.1016/j.catcom.2014.05.031Copyright: 2014 Elsevier. This is an ABSTRACT ONLY. The definitive version is published in Catalysis Communications, vol. 54(5), pp 118-123An efficient room temperature catalyzed oxidation of cyclohexane to cyclohexanone (K) and cyclohexanol (A) was achieved over hetero-mixed tungsten–vanadia (WO(sub3)/V(sub2)O(sub5)) using H(sub2)O(sub2) oxidant. WO(sub3)/V(sub2)O(sub5) exhibited high catalytic activity to initiate the free-radical oxyfunctionalization of cyclohexane to afford up to 90% conversions within 6 h. The KA selectivity was found to depend on reaction time and the amount of catalyst. The WO(sub3)/V(sub2)O(sub5) catalyst was highly recyclable with consistent catalytic activity.enVanadiumTungstenCyclohexanOxidationHetero-mixedNanostructuredArticleMakgwane, P. R., & Ray, S. (2014). Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. http://hdl.handle.net/10204/7682Makgwane, Peter R, and SS Ray "Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst." (2014) http://hdl.handle.net/10204/7682Makgwane PR, Ray S. Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. 2014; http://hdl.handle.net/10204/7682.TY - Article AU - Makgwane, Peter R AU - Ray, SS AB - An efficient room temperature catalyzed oxidation of cyclohexane to cyclohexanone (K) and cyclohexanol (A) was achieved over hetero-mixed tungsten–vanadia (WO(sub3)/V(sub2)O(sub5)) using H(sub2)O(sub2) oxidant. WO(sub3)/V(sub2)O(sub5) exhibited high catalytic activity to initiate the free-radical oxyfunctionalization of cyclohexane to afford up to 90% conversions within 6 h. The KA selectivity was found to depend on reaction time and the amount of catalyst. The WO(sub3)/V(sub2)O(sub5) catalyst was highly recyclable with consistent catalytic activity. DA - 2014-09 DB - ResearchSpace DP - CSIR KW - Vanadium KW - Tungsten KW - Cyclohexan KW - Oxidation KW - Hetero-mixed KW - Nanostructured LK - https://researchspace.csir.co.za PY - 2014 SM - 1566-7367 T1 - Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst TI - Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst UR - http://hdl.handle.net/10204/7682 ER -