Wellington, Kevin WGovindjee, Varsha PSteenkamp, Paul2019-03-072019-03-072018-12Wellington, K.W., Govindjee, V.P., Steenkamp, P. 2018. A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. Journal of Catalysis, v. 368, pp 306-314.0021-9517http://hdl.handle.net/10204/10753Copyright: 2018 Elsevier. Due to copyright restrictions, the attached PDF file contains the abstract of the published item only. For access to the published item, kindly consult the publisher's website. The definitive version of the is published at https://doi.org/10.1016/j.jcat.2018.10.014A commercial laccase, Suberase from Novozymes, catalyses the synthesis of triaminated cyclohexa-2,4-dienones and a methylbenzene-1,2-diol derivative. The primary amine (analine) and the catechol was reacted under mild conditions (40C) in a reaction vessel open to air in the presence of Suberase and a co-solvent (DMF) at pH 6.0. This reaction was also conducted using an environmentally friendly cosolvent (EtOH). Triamination is favoured over diamination and monoamination.enLaccaseCatecholsAnalinesCyclohexa-2,4-dienonesC-N bond formationGreen chemistryA laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catecholArticleWellington, K. W., Govindjee, V. P., & Steenkamp, P. (2018). A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. http://hdl.handle.net/10204/10753Wellington, Kevin W, Varsha P Govindjee, and Paul Steenkamp "A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol." (2018) http://hdl.handle.net/10204/10753Wellington KW, Govindjee VP, Steenkamp P. A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol. 2018; http://hdl.handle.net/10204/10753.TY - Article AU - Wellington, Kevin W AU - Govindjee, Varsha P AU - Steenkamp, Paul AB - A commercial laccase, Suberase from Novozymes, catalyses the synthesis of triaminated cyclohexa-2,4-dienones and a methylbenzene-1,2-diol derivative. The primary amine (analine) and the catechol was reacted under mild conditions (40C) in a reaction vessel open to air in the presence of Suberase and a co-solvent (DMF) at pH 6.0. This reaction was also conducted using an environmentally friendly cosolvent (EtOH). Triamination is favoured over diamination and monoamination. DA - 2018-12 DB - ResearchSpace DP - CSIR KW - Laccase KW - Catechols KW - Analines KW - Cyclohexa-2,4-dienones KW - C-N bond formation KW - Green chemistry LK - https://researchspace.csir.co.za PY - 2018 SM - 0021-9517 T1 - A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol TI - A laccase-catalysed synthesis of triaminated cyclohexa-2,4-dienones from catechol UR - http://hdl.handle.net/10204/10753 ER -