dc.contributor.author |
Ren, Jianwei
|
|
dc.contributor.author |
Musyoka, Nicholas M
|
|
dc.contributor.author |
Langmi, Henrietta W
|
|
dc.contributor.author |
North, Brian C
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|
dc.contributor.author |
Mathe, Mahlanyane K
|
|
dc.contributor.author |
Kang, X
|
|
dc.date.accessioned |
2014-11-18T10:14:54Z |
|
dc.date.available |
2014-11-18T10:14:54Z |
|
dc.date.issued |
2014-09 |
|
dc.identifier.citation |
Ren, J., Musyoka, N.M., Langmi, H.W., North, B.C., Mathe, M. and Kang, X. 2014. Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage. International Journal of Hydrogen Energy, vol. 39(27), pp 14912-14917 |
en_US |
dc.identifier.issn |
0360-3199 |
|
dc.identifier.uri |
http://ac.els-cdn.com/S0360319914020151/1-s2.0-S0360319914020151-main.pdf?_tid=139e16fe-6a4d-11e4-a368-00000aab0f02&acdnat=1415784180_535b03b0b53378ce326bdb5730653126
|
|
dc.identifier.uri |
http://hdl.handle.net/10204/7777
|
|
dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S0360319914020151
|
|
dc.identifier.uri |
https://doi.org/10.1016/j.ijhydene.2014.07.056
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|
dc.description |
Copyright: 2014 Elsevier. This is an ABSTRACT ONLY. The definitive version is published in International Journal of Hydrogen Energy, vol. 39(27), pp 14912-14917 |
en_US |
dc.description.abstract |
The fabrication of coreeshell nanocrystals by incorporating microporous UiO-66 into mesoporous MIL-101 is reported. The growth of the coreeshell MIL-101@UiO-66 nanocrystals was observed and supported by TEM and PXRD. The accessible pore volumes of the individual metal-organic framework (MOF) components and the coreeshell hybrid crystals were also characterized. The hydrogen storage capacity exhibited by the resulting core eshell nanocrystals was 26% and 60% higher than those of pure phase MIL-101 and UiO-66, respectively. Finally, the fabricated coreeshell MIL-101@UiO-66 structure exhibited a high degree of moisture tolerance. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsevier |
en_US |
dc.relation.ispartofseries |
Workflow;13356 |
|
dc.subject |
Metal-organic framework |
en_US |
dc.subject |
MOF |
en_US |
dc.subject |
Core-shell MOFs |
en_US |
dc.subject |
Moisture tolerance |
en_US |
dc.subject |
Hydrogen storage |
en_US |
dc.title |
Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage |
en_US |
dc.type |
Article |
en_US |