dc.contributor.author |
Adekunle, AS
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|
dc.contributor.author |
Ozoemena, KI
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|
dc.date.accessioned |
2011-03-30T10:32:50Z |
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dc.date.available |
2011-03-30T10:32:50Z |
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dc.date.issued |
2010-12 |
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dc.identifier.citation |
Adekunle, AS and Ozoemena, KI. 2010. Voltammetric and impedimetric properties of nano-scaled -Fe2O3 catalysts supported on multi-walled carbon nanotubes: catalytic detection of dopamine. International Journal of Electrochemical Science, Vol. 5, pp 1726-1742 |
en_US |
dc.identifier.issn |
1452-3981 |
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dc.identifier.uri |
http://www.electrochemsci.org/papers/vol5/5121726.pdf
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|
dc.identifier.uri |
http://hdl.handle.net/10204/4939
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dc.description |
Copyright: 2010 Electrochemical Science Group |
en_US |
dc.description.abstract |
The electron transfer and electrocatalytic proiperties of iron oxide nanoparticle (g-Fe2O3) catalysts supported on MWCNTs are described. The MWCNT-Fe2O3 and its electrodes were successfully characterised with FESEM, HRTEM, XRD, EDX, cyclic voltammetry and electrochemical impedance spectroscopy. The MWCNT-Fe2O3 based electrodes demonstrated fastest electron transport and current response towards DA compared to other electrodes studied, giving a catalytic rate constant of 16.4 x 105 cm3mol-1s-1, sensitivity of 0.026 AM-1 and limit of detection of 3.3 x 10-7 M. The electrode may be potentially useful for the detection of DA in real drug sample analysis. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Electrochemical Science Group |
en_US |
dc.relation.ispartofseries |
Workflow request;6134 |
|
dc.subject |
MWCNTs |
en_US |
dc.subject |
Iron oxide nanoparticles |
en_US |
dc.subject |
Voltammetry |
en_US |
dc.subject |
Electrochemical impedance spectroscopy |
en_US |
dc.subject |
Dopamine detection |
en_US |
dc.subject |
Electrochemical science |
en_US |
dc.subject |
Electrochemicals |
en_US |
dc.title |
Voltammetric and impedimetric properties of nano-scaled -Fe2O3 catalysts supported on multi-walled carbon nanotubes: catalytic detection of dopamine |
en_US |
dc.type |
Article |
en_US |