Alloyed electrocatalysts such as PtNi/C[1-2], PtCo/C[3], PtCr/C[4], PtFe/C [5-6], and non-alloyed Pt-TiO2/C were reportedly investigated for methanol tolerance during Oxygen reduction reaction (ORR). The high methanol tolerance of these electrocatalysts during the ORR was attributed to a composition effect, disordered stucture and low activity for methanol oxidation reaction. Most Pt alloy electrocatalysts were prepared via a complex procedure or by high temeperature thermal reduction. In this work, Pt3Ni/C alloy electrocatalysts were synthesised by a simple route at low temperature, resulting in a highly-alloyed product with high ORR activity and excellent methanol tolerance
Reference:
Zheng, H, Rohwer, M and Mathe, M. 2010. Oxygen reduction reaction on a highly-alloyed Pt-Ni supported carbon electrocatalyst in acid solution. CSIR 3rd Beinnual Conference 2010, Science Real and Relevant, CSIR International Convention Center, Pretoria, South Africa, pp 1
Zheng, H., Rohwer, M. B., & Mathe, M. K. (2010). Oxygen reduction reaction on a highly-alloyed Pt-Ni supported carbon electrocatalyst in acid solution. CSIR. http://hdl.handle.net/10204/4238
Zheng, Haitao, Mark B Rohwer, and Mahlanyane K Mathe. "Oxygen reduction reaction on a highly-alloyed Pt-Ni supported carbon electrocatalyst in acid solution." (2010): http://hdl.handle.net/10204/4238
Zheng H, Rohwer MB, Mathe MK, Oxygen reduction reaction on a highly-alloyed Pt-Ni supported carbon electrocatalyst in acid solution; CSIR; 2010. http://hdl.handle.net/10204/4238 .
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