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Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6)

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dc.contributor.author Liles, DC en_US
dc.contributor.author Verhoeven, PFM en_US
dc.date.accessioned 2007-02-08T08:06:08Z en_US
dc.date.accessioned 2007-06-07T10:06:20Z
dc.date.available 2007-02-08T08:06:08Z en_US
dc.date.available 2007-06-07T10:06:20Z
dc.date.issued 1996-09-06 en_US
dc.identifier.citation Liles, DC and Verhoeven, PFM. 1996. Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6). Journal of Organometallic Chemistry, vol. 522(1), pp 33-38 en_US
dc.identifier.issn 0022-328X en_US
dc.identifier.uri http://hdl.handle.net/10204/1665 en_US
dc.identifier.uri http://hdl.handle.net/10204/1665
dc.description.abstract Treatment of [RuHL (5)] (+) (L = PMe (2) Ph) with phenylacetylene in ethanol yielded the dimerization of HC=CPh to (Z)-1, 4-diphenylbut-3-en-1-yne. The molecular structure of [Ru(eta(3)-PhC(3)CHPh)L(4)](PF6) (L = PMe(2)Ph) (2) shows a seven-coordinate environment at ruthenium; the eta(3)-butenynyl moiety is both sigma- and pi-coordinated to the metal centre. Low-temperature P-31 NMR data for some [Ru(C=CR)L(4)](PF6) complexes with R = Ph, CO(2)Et, SiMe(3), (t)Bu and L = PMe(2)Ph are discussed. en_US
dc.format.extent 684971 bytes en_US
dc.format.mimetype application/pdf en_US
dc.language.iso en en_US
dc.publisher Elsevier Science SA en_US
dc.rights Copyright: 1996 Elsevier Science SA en_US
dc.subject Rutheniums en_US
dc.subject X-ray diffraction en_US
dc.subject Crystal structures en_US
dc.subject Alkynes dimerization en_US
dc.subject Chemistry en_US
dc.title Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6) en_US
dc.type Article en_US
dc.identifier.apacitation Liles, D., & Verhoeven, P. (1996). Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6). http://hdl.handle.net/10204/1665 en_ZA
dc.identifier.chicagocitation Liles, DC, and PFM Verhoeven "Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6)." (1996) http://hdl.handle.net/10204/1665 en_ZA
dc.identifier.vancouvercitation Liles D, Verhoeven P. Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6). 1996; http://hdl.handle.net/10204/1665. en_ZA
dc.identifier.ris TY - Article AU - Liles, DC AU - Verhoeven, PFM AB - Treatment of [RuHL (5)] (+) (L = PMe (2) Ph) with phenylacetylene in ethanol yielded the dimerization of HC=CPh to (Z)-1, 4-diphenylbut-3-en-1-yne. The molecular structure of [Ru(eta(3)-PhC(3)CHPh)L(4)](PF6) (L = PMe(2)Ph) (2) shows a seven-coordinate environment at ruthenium; the eta(3)-butenynyl moiety is both sigma- and pi-coordinated to the metal centre. Low-temperature P-31 NMR data for some [Ru(C=CR)L(4)](PF6) complexes with R = Ph, CO(2)Et, SiMe(3), (t)Bu and L = PMe(2)Ph are discussed. DA - 1996-09-06 DB - ResearchSpace DP - CSIR KW - Rutheniums KW - X-ray diffraction KW - Crystal structures KW - Alkynes dimerization KW - Chemistry LK - https://researchspace.csir.co.za PY - 1996 SM - 0022-328X T1 - Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6) TI - Synthesis, P-31 NMR data and X-ray analysis of a ruthenium(II) dimethylphenylphosphine complex with dimerized phenylacetylene: The structure of [(PhMe(2)P)(4)Ru(eta(3)-PhC(3)CHPh)](PF6) UR - http://hdl.handle.net/10204/1665 ER - en_ZA


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