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Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters

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dc.contributor.author Zeevaart, JG en_US
dc.contributor.author Parkinson, CJ en_US
dc.contributor.author De Koning, CB en_US
dc.date.accessioned 2007-02-06T09:17:11Z en_US
dc.date.accessioned 2007-06-07T10:05:01Z
dc.date.available 2007-02-06T09:17:11Z en_US
dc.date.available 2007-06-07T10:05:01Z
dc.date.copyright en_US
dc.date.issued 2004-05-24 en_US
dc.identifier.citation Zeevaart, JG, Parkinson, CJ and De Koning, CB. 2004. Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters. Tetrahedron Letters, vol. 45(22), pp 4261-4264 en_US
dc.identifier.issn 0040-4039 en_US
dc.identifier.uri http://hdl.handle.net/10204/1502 en_US
dc.identifier.uri http://hdl.handle.net/10204/1502
dc.description.abstract The coupling reaction between ethyl acetoacetate and a number of aryl halides in the presence of palladium acetate, a bulky and electron rich phosphine and K3PO4 is described. The arylated acetoacetate ester is de-acylated under the reaction conditions resulting in the generation of 2-arylacetic acid esters, constituting a mild alternative to direct arylation of carboxylate esters. en_US
dc.format.extent 256012 bytes en_US
dc.format.mimetype application/pdf en_US
dc.language.iso en en_US
dc.publisher Pergamon-Elsevier Science Ltd en_US
dc.rights Copyright: 2004 Pergamon-Elsevier Science Ltd en_US
dc.source en_US
dc.subject Palladium catalysis en_US
dc.subject Enolate arylation en_US
dc.subject Arylacetic acid esters en_US
dc.subject Organic chemistry en_US
dc.title Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters en_US
dc.type Article en_US
dc.identifier.apacitation Zeevaart, J., Parkinson, C., & De Koning, C. (2004). Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters. http://hdl.handle.net/10204/1502 en_ZA
dc.identifier.chicagocitation Zeevaart, JG, CJ Parkinson, and CB De Koning "Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters." (2004) http://hdl.handle.net/10204/1502 en_ZA
dc.identifier.vancouvercitation Zeevaart J, Parkinson C, De Koning C. Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters. 2004; http://hdl.handle.net/10204/1502. en_ZA
dc.identifier.ris TY - Article AU - Zeevaart, JG AU - Parkinson, CJ AU - De Koning, CB AB - The coupling reaction between ethyl acetoacetate and a number of aryl halides in the presence of palladium acetate, a bulky and electron rich phosphine and K3PO4 is described. The arylated acetoacetate ester is de-acylated under the reaction conditions resulting in the generation of 2-arylacetic acid esters, constituting a mild alternative to direct arylation of carboxylate esters. DA - 2004-05-24 DB - ResearchSpace DP - CSIR KW - Palladium catalysis KW - Enolate arylation KW - Arylacetic acid esters KW - Organic chemistry LK - https://researchspace.csir.co.za PY - 2004 SM - 0040-4039 T1 - Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters TI - Palladium-catalysed arylation of acetoacetate esters to yield 2-arylacetic acid esters UR - http://hdl.handle.net/10204/1502 ER - en_ZA


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