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In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF)

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dc.contributor.author Ren, Jianwei
dc.contributor.author Musyoka, Nicholas M
dc.contributor.author Langmi, Henrietta W
dc.contributor.author Walker, J
dc.contributor.author Mathe, Mahlanyane K
dc.contributor.author Liao, S
dc.date.accessioned 2019-07-05T10:18:27Z
dc.date.available 2019-07-05T10:18:27Z
dc.date.issued 2018-10
dc.identifier.citation Ren, J. et al. 2018. In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF). Polyhedron, vol. 153: 205-212 en_US
dc.identifier.issn 0277-5387
dc.identifier.uri https://doi.org/10.1016/j.poly.2018.07.026
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S0277538718304133
dc.identifier.uri http://hdl.handle.net/10204/11023
dc.description Copyright: 2018 Elsevier. Due to copyright restrictions, the attached PDF file contains the accepted version of the published item. For access to the published version, please consult the publisher's website. en_US
dc.description.abstract In this work, in-situ IR monitoring technique was employed to monitor the crystallization process of Zrfumarate (Zr-fum) MOF in both H2O- and DMF-based systems. Wherein, the acid modulator (HCOOH) was only observed to be consumed in the DMF-based synthesis. Further solid-state NMR ex-situ results suggested the participations of HCOOH in the Zr-fum MOF structure formation, resulting in the possibility of formation of structural defects. This observation will further help to understand the formation of MOF structural defects from different solvent systems. en_US
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.relation.ispartofseries Worklist;21426
dc.subject Structural defects en_US
dc.subject Zr-fumarate MOF en_US
dc.subject In-situ IR monitoring en_US
dc.subject Solvent-dependent en_US
dc.title In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF) en_US
dc.type Article en_US
dc.identifier.apacitation Ren, J., Musyoka, N. M., Langmi, H. W., Walker, J., Mathe, M. K., & Liao, S. (2018). In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF). http://hdl.handle.net/10204/11023 en_ZA
dc.identifier.chicagocitation Ren, Jianwei, Nicholas M Musyoka, Henrietta W Langmi, J Walker, Mahlanyane K Mathe, and S Liao "In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF)." (2018) http://hdl.handle.net/10204/11023 en_ZA
dc.identifier.vancouvercitation Ren J, Musyoka NM, Langmi HW, Walker J, Mathe MK, Liao S. In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF). 2018; http://hdl.handle.net/10204/11023. en_ZA
dc.identifier.ris TY - Article AU - Ren, Jianwei AU - Musyoka, Nicholas M AU - Langmi, Henrietta W AU - Walker, J AU - Mathe, Mahlanyane K AU - Liao, S AB - In this work, in-situ IR monitoring technique was employed to monitor the crystallization process of Zrfumarate (Zr-fum) MOF in both H2O- and DMF-based systems. Wherein, the acid modulator (HCOOH) was only observed to be consumed in the DMF-based synthesis. Further solid-state NMR ex-situ results suggested the participations of HCOOH in the Zr-fum MOF structure formation, resulting in the possibility of formation of structural defects. This observation will further help to understand the formation of MOF structural defects from different solvent systems. DA - 2018-10 DB - ResearchSpace DP - CSIR KW - Structural defects KW - Zr-fumarate MOF KW - In-situ IR monitoring KW - Solvent-dependent LK - https://researchspace.csir.co.za PY - 2018 SM - 0277-5387 T1 - In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF) TI - In-situ IR monitoring to probe the formation of structural defects in Zr-fumarate metal-organic framework (MOF) UR - http://hdl.handle.net/10204/11023 ER - en_ZA


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