Author:Thackeray, MM; Rossouw, MH; Gummow, RJ; Liles, DC; Pearce, K; De Kock, A; David, WIF; Hull, sDate:Jun 1993A pure and highly crystalline form of ramsdellite-MnO2 has been synthesized by acid treatment of the spinels LiMn2O4 and Li2Mn4O9 at 95°C. Although the ramsdellite-MnO2 framework remains intact on lithiation at 70°C, the hexagonally-close-packed ...Read more
Author:Thackeray, MM; Rossouw, MH; De Kock, A; De la Harpe, AP; Gummow, RJ; Pearce, K; Liles, DCDate:15 Mar 1993Manganese dioxide has for many years found widespread use as a cathode material in aqueous Leclanche, zinc chloride and alkaline cells and, more recently, in nonaqueous lithium cells. However, despite the large number of polymorphic structures ...Read more